The purpose of hardening is to obtain a hard martensitic or sometimes bainitic structure. It includes austenitization, rapid cooling and tempering. Depending on the type of material, the shape and cross-section of details as well as the operational requirements, we perform vacuum volumetric hardening with cooling in oil or gases under high pressure, which ensures lower deformation and, consequently, allows to reduce the grinding allowance. In two-chamber vacuum furnaces, cooling takes place in the latest generation GTL-based vacuum oil, which is particularly effective for larger-sized details made of low-hardening steel.
The use of FINECARB® technology allows to obtain optimal parameters of the surface layer because of the elimination of internal oxidation and uncontrolled, unfavourable precipitation. An additional effect is the reduction of deformation of elements during their heat treatment. We offer the implementation of processes in single-chamber vacuum furnaces, in which both the carburizing and hardening processes take place in the same chamber, as well as in two-chamber vacuum furnaces, where the carburizing process is carried out in one chamber, the so-called "Heating chamber", and the hardening process in the second chamber, the so-called "Cooling chamber", connected with a quenching bath. Low-pressure carburizing of steel with the FineCarb® technology guarantees the achievement of the assumed thickness of the surface layers in a much shorter time compared to gas carburizing, as well as full control and repeatability of the processes. After the carburizing stage, we can harden in vacuum oil or nitrogen in high pressure.
The purpose
of hardening is to obtain a hard martensitic or sometimes bainitic structure.
These structures can only arise from austenite, therefore, in the process of
hardening the steel, it must be heated to the temperature at which austenite is
formed. Hypereutectoid steels are heated to temperatures from 30 to 50°C above
Ac3, while hypereutectoid steels- to temperatures from 30 to 50°C above Ac1.
Hardening of hypereutectoid steels with heating to the austenite / cementite
two-phase range occurs because the hard cementite provides high abrasion
resistance. Dissolving cementite while heating the steel in the hardening
process would be pointless, as it would lead to a reduction in hardness due to
an increase in the amount of residual austenite and loss of strengthening with
cementite particles. At the same time, there would be an increase in the
austenite grain, an increase in scale losses and a higher energy consumption
(higher furnace temperature). In the process of steel hardening, it should be
cooled from the austenitizing temperature at a rate which ensures that the
changes in the diffusion range are avoided (at a rate greater than or equal to
the so-called critical rate at which martensitic or bainitic transformation
occurs). A simple solution to avoid the formation of high stresses causing
deformation of the workpiece, and sometimes also its fracture, is gradual
hardening, which consists of holding the detail at a temperature above Ms until
the temperature equalizes in the cross-section and then on slow cooling,
ensuring the simultaneous occurrence of martensitic transformation in the
entire cross-section.
Depending
on the type of material, the shape and cross-section of the details as well as
the operational requirements, hardening can be performed in oils or gases under
high pressure. It ensures smaller and more repeatable deformations and,
consequently, allows to reduce the grinding allowance.
After
hardening, steel gains hardness and strength, its yield point and elasticity
increase. However, its impact strength, elongation, contraction and
machinability decrease.
Steels with
austenitic structure, as well as other alloys - mainly of non-ferrous metals -
which do not show allotropic changes but are characterized by variable
solubility of one of the components in a solid solution, can be subjected to
precipitation hardening.
We offer
processes that are combined technological operations:
• supersaturation
• aging
Supersaturation
It consists
of heating the alloy to a temperature higher by approx. 30÷50°C than the limit
of solubility to dissolve the separated component (in steels, most often
tertiary cementite) in a solid solution, heating at this temperature and then
cooling rapidly. As a result of supersaturation, the alloy obtains a
single-phase structure. In the case of austenitic steels, the structure is
austenite supersaturated with carbon. The strength properties of steel after supersaturation
are slightly reduced, but plastic properties increase.
Aging
It consists
of heating the previously supersaturated alloy to a temperature lower than the
limit of solubility, heating at this temperature and cooling it down. During
the aging process, the excess component in the supersaturated solid solution is
released in the form of highly dispersed phases. In some cases, the aging
involves intermediate phases and Guinier-Preston zones, in which they segregate
atoms dissolved in the solvent. Aging causes strengthening, shown by an
increase in strength properties and a decrease in plastic properties. When the
temperature is too high, the aging effect occurs, consisting in coagulation of
the precipitates and the loss of their coherence, which does not increase the
hardness in relation to the supersaturated state, but on the contrary - reduces
it. Sometimes aging occurs at room temperature, then it is called spontaneous
aging.
Aging can
also be an undesirable process, e.g., in deep drawing sheets and boiler steels,
as it reduces plastic properties and increases brittleness.
A method of
heat treatment of the material, which usually involves heating the steel to a
specific temperature, heating it at this temperature and cooling it to obtain
structures close to the equilibrium state. One can distinguish between
recrystallization annealing, homogenization, stress relief, complete,
isothermal and spheroidizing annealing. In the field of annealing, we carry out
orders from a wide range of services.